| United
States Patent |
5,081,171
|
| Nixon |
January
14, 1992
|
Nixon January 14, 1992
Composition for sealing of painted or metal surfaces
Abstract
A
liquid composition for protecting a positively charged surface,
the composition comprising: negatively charged polytetrafluoroethylene
(ptfe) polymer resin particles and at least one member of the group
consisting of methyltrimethoxysilane and an amino functional polysiloxane;
whereby the negatively charged polytetrafluoroethylene molecules
fuse to the surface upon exposure to ambient temperatures above
about 68 degrees Fahrenheit.
Inventors:
Nixon; Charles R.
Appl. No.: 311150
Filed: February 14, 1989
| Current
U.S. Class: |
524/188;
524/265; 524/546
|
| Intern'l
Class: |
C08K
005/54; C08L 027/18
|
| Field
of Search: |
524/546,261,262,506,188,265
427/13,387
|
References
Cited [Referenced By]
U.S.
Patent Documents
| 3560249 |
Feb.,
1971 |
Chereshkevich
et al. |
427/13.
|
| 3925292 |
Dec.,
1975 |
Holmes |
524/546.
|
| 3968069 |
Jul.,
1976 |
Grimand
et al. |
524/546.
|
| 4104225 |
Aug.,
1978 |
Combere |
524/546.
|
| 4284668 |
Aug.,
1981 |
Nixon |
427/355.
|
Other
References
Dow Corning, "A Guide to Dow Corning.RTM.
Silicones for Polish Formulators", Form No. 22-637A-79, 1979.
Dow Corning, "Information About Polish Ingredients", Form
No. 22-240A-78, 1978.
Dow Corning, Material Safety Data Sheet for "Dow Corning.RTM.
531 Fluid", May 15, 1987.
Dow Corning, Material Safety Data Sheet for "Dow Corning.RTM.
536 Fluid", Mar. 26, 1990.
Primary
Examiner: Lawrence; Evan
Attorney, Agent or Firm: Volpe & Koenig
Description
BACKGROUND
OF THE INVENTION
This
invention relates to sealants for metal or painted surfaces, including
the gel coat on fiberglass, to protect the surfaces from corrosion
and other damaging environmental effects. The present invention
is particularly useful as a paint sealant for automobiles, airplanes
or boats. Unprotected painted surfaces and unpainted metal surfaces
are damaged by exposure to the environment by the action of ultra-violet
and infra-red rays of the sun, acid rain, salt, insects and other
harmful elements.
In
the Past: There have been numerous products developed for
protecting painted surfaces, such as waxes, activated silicone polyethylene
polymers and, as described in U.S. Pat. No.
4,284,668, tetrafluoroethylene polymers. In that process
a paint sealant composition in the form of a tetrafluoroethylene
monomer and an abrasive compound are applied to the painted surface.
The surface is then buffed so that the buffing action in conjunction
with the abrasive compound produces sufficient heat to polymerize
the tetrafluoroethylene monomer, thereby creating a protective layer
of polymer over the painted surface.
It
has been found in practice that the utilization of the abrasive
and buffing action requires substantial skill by the applicator,
and that improper application of the composition results in damage
to the paint or removal of the paint from the surface. Furthermore,
a three-step process is involved, namely cleaning the surface, applying
the tetrafluoroethylene monomer, and eventually applying a protective
coating.
In
the Present: SUMMARY OF OUR INVENTION
U.S. Pat. No. 5,081,171
The
present invention (PPS) is directed towards novel protective compositions
and a method of applying same to a painted surface, including gel
coats of fiberglass surfaces, or unpainted metal surface. The protective
composition comprises negatively charged polytetrafluoroethylene
(hereinafter "PTFE") polymer resin particles, preferably
in an aqueous dispersion in the form of a hydrophobic colloid with
resin particles of about 0.05 to about 0.5 microns or larger in
size.
Before
application of the protective composition, the painted or metal
surface is positively charged, preferably with a novel cleaning
composition which removes any trapped sediments and insolvents from
the pores in the paint or metal surface and which leaves the surface
positively charged by virtue of using a cationic surfactant containing
electropositive ions. (Step 1)
The
molecules of PTFE resin, which are negatively charged, i.e. containing
negative ions, are pulled down into the pores in the surface of
the paint or metal in view of the electrostatic attraction between
the negatively charged molecules and the positively charged surface.
As the treated surface is allowed to cure in a warm environment,
the PTFE resin molecules elongate, causing them to physically interlock
themselves to each other and fuse into the paint or metal surface.
(Step 2)
The
PTFE is inert to most harmful elements except halogen fluorene.
In particular the action of ultra-violet and infra-red rays, photolysis,
acidic and alkaline chemicals are resisted by the PTFE protective
coating. The present invention therefore provides
durability and resistance to the damaging effect of environmental
elements, in combination with a very simple method
of application.
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